LCW has a simple structure based on electoral representation
- The General Assembly groups the elected presidents of the member organizations, which in turn elect every four years
- An Administrative Committee consisting of a president, four vice-presidents, a secretary, a treasurer, and a representative before the government

A representative for each of the six Lebanese districts:
1. the Beirut district
2. the Bekaa district
3. the Mount Lebanon district
4. the Nabatyeh district,
5. the North Lebanon district
6. the South Lebanon district

A chairperson for each of the six following committees:
1. The Committee for Arab and International Relations
2. The Financial Committee
3. The Legal Committee,
4. The Committee for Media and Culture
5. The Committee for Planning and Studies
6. The Committee for Social Affairs

- The Council appoints an Advisory Board.
- An Administrative Committee was elected May 2004 with a mandate until May 2008
- The Administrative Committee of the Lebanese Council of Women 2004-2008

- President: Faikaa Turkiyeh
- Vice-Presidents: - Sana Solh Lamia 
                            - Osseiran Nada Soubra 
                            - Ikbal Shayeb Ghanem
- Secretary - Treasurer: Fadila Fattal Oumaya Zaatari

Chairpersons of the committees:
Regional representatives:
- For Arab and Int’l Relations: Hiam Bizri Shreif
- For the Beirut region: Najwa Ramadan
- For Finance: Fadia Osman Al Assad
- For the Bekaa region: Dunia Khoury
- For Legal Affairs: Aida Nasrallah Helwani
- For Mount Lebanon: Lina Abdel Samad
- For Media and culture: Linda Saab
- For Nabatiyeh: Salma Ali Ahmad
- For Planning and Studies: Nada Saad
- For North Lebanon: Fatima Badawi
- For Social Affairs: Emilda Yousef
- For South Lebanon: Asma Dirani
 The pioneer leaders and presidents of the Lebanese Council of Women:
- Labiba Tabet
- Adèle Nakhou
- Ibtihaj Kaddoura
- Rose Shihaa
- Evelyn Boustros
- Laure Tabet
- Najla Saab
- Emily Fares Ibrahim
- Aman Shaarani
- Linda Mattar
- Ikbal Murad Doughan
- Faikaa Turkiyeh